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CAS RN: 12154-84-6 | Product Number: A2981

(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)


Purity:
Synonyms:
  • Ir(acac)(COD)
Documents:
200MG
$96.00
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1G
$330.00
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* The storage conditions are subject to change without notice.


Product Number A2981
Molecular Formula / Molecular Weight C__1__3H__1__9IrO__2 = 399.51  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
CAS RN 12154-84-6
Reaxys Registry Number 14337429
PubChem Substance ID 354333737
MDL Number

MFCD08273779

Specifications
Appearance Light yellow to Amber to Dark green powder to crystaline
Elemental analysis(Carbon) 37.10 to 41.00 %
Properties (reference)
Melting Point 155 °C
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
RTECS# NO3615000
Transport Information:
H.S.code* 2843.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
ortho-Selective C-H Silylation of Aryl Compounds Using an Iridium Catalyst

A2981

Experimental procedure (R = Ph)1):
A mixture of Ir(acac)(COD) (4.0 mg, 0.010 mmol), 2-phenylpyridine (31.0 mg, 0.200 mmol), fluorodiphenylsilane (56.6 mg, 0.280 mmol), and 2-norbornene (75.3 mg, 0.800 mmol) in toluene (1.0 mL) is stirred at 115 °C for 24 h. Upon completion of the reaction, the crude product is purified by column chromatography on silica gel (hexane:EtOAc = 9:1) to afford pure 1 as a white solid (66.2 mg, 93%).

References


PubMed Literature


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