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CAS RN: 72824-04-5 | Product Number: A2157

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)


Purity: >96.0%(GC)
Synonyms:
  • Allylboronic Acid Pinacol Ester (stabilized with Phenothiazine)
Documents:
1G
$32.00
16   2  
5G
$94.00
11   2  

* Please contact our distributors or TCI to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.


Product Number A2157
Purity / Analysis Method >96.0%(GC)
Molecular Formula / Molecular Weight C__9H__1__7BO__2 = 168.04  
Physical State (20 deg.C) Liquid
Storage Temperature <0°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive,Heat Sensitive
CAS RN 72824-04-5
Reaxys Registry Number 4244068
PubChem Substance ID 87560602
MDL Number

MFCD00013347

Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 96.0 %
Properties (reference)
Boiling Point 35 °C/1 mmHg
Flash point 46 °C
Specific Gravity (20/20) 0.89
Refractive Index 1.43
GHS
Pictogram Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H412 : Harmful to aquatic life with long lasting effects.
H226 : Flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P273 : Avoid release to the environment.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P403 + P235 : Store in a well-ventilated place. Keep cool.
Related Laws:
Transport Information:
UN Number UN3272
Class 3
Packing Group III
H.S.code* 2931.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Allylation of Aromatics Using the Suzuki-Miyaura Cross-Coupling Reaction

References

S. Kotha, M. Behera, V. R. Shah, Synlett 2005, 1877.


PubMed Literature


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