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CAS RN: 3375-31-3 | Product Number: A1424

Palladium(II) Acetate


Purity: >98.0%(T)
Synonyms:
  • Acetic Acid Palladium(II) Salt
Documents:
1G
$77.00
≥20  ≥20 
5G
$256.00
≥20  ≥20 

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* The storage conditions are subject to change without notice.


Product Number A1424
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__4H__6O__4Pd = 224.51  
Physical State (20 deg.C) Solid
CAS RN 3375-31-3
Reaxys Registry Number 3375313
PubChem Substance ID 87562878
SDBS (AIST Spectral DB) 12841
Merck Index (14) 6991
MDL Number

MFCD00012453

Specifications
Appearance Light yellow to Amber to Dark green powder to crystal
Purity(Chelometric Titration) 98.0 to 102.0 %
Properties (reference)
Maximum Absorption Wavelength 400(EtOH) nm
Solubility (soluble in) Acetone
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H318 : Causes serious eye damage.
Precautionary Statements P280 : Wear eye protection/ face protection.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Related Laws:
RTECS# AJ1900000
Transport Information:
H.S.code* 2843.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Regioselective C-H Coupling Reaction of Benzo[h]quinoline and Arene Compounds

Typical Procedure:
Palladium(II) acetate (9.6 mg, 0.048 mmol), 1,4-benzoquinone (23.7 mg, 0.22 mmol), silver(I) carbonate (237.2 mg, 0.86 mmol) and benzo[h]quinoline (0.43 mmol) are weighed into a 20 mL scintillation vial. After adding 1,2-dichlorobenzene (3.75 mL), 125 µL of DMSO (1.45 mmol) is added. The resulting mixture is sealed with a teflon-lined cap, and vigorously stirred at 130 °C. The reaction mixture turns grey/brown upon heating. The reaction is cooled to room temperature, filtered through a plug of silica, and the silica is washed with copious AcOEt (150 mL). The filtrate is concentrated and then evaporated to dryness under high vacuum, and the resulting residue is purified by column chromatography (SiO2, AcOEt : hexane = 2 : 98) to afford the desired product as a pale yellow solid (130 mg, Y. 93%).

References


Application
Arylations of Indoles

References

M. Miyasaka, A. Fukushima, T. Satoh, K. Hirano, M. Miura, Chem. Eur. J. 2009, 15, 3674.


Application
Palladium-Catalyzed One-Pot Synthesis of Indoles from 2-Iodobenzoic Acid

References

O. Leogane, H. Lebel, Angew. Chem. Int. Ed. 2007, 47, 350.


Application
Synthesis of aromatic esters via Pd-catalyzed decarboxylative coupling with bidentate phosphine ligands

Typical procedure:
A 10 mL oven-dried Schlenk tube is charged with Pd(OAc)2 (0.005 mmol), 1,3-bis(diphenylphosphino)propane (0.0075 mmol), and potassium ethyl oxalate (0.75 mmol). The tube is evacuated and backfilled with argon. Bromobenzene (0.5 mmol) and 1-methyl-2-pyrrolidone (1.0 mL), are added by syringe at room temperature. The tube is then sealed and the mixture is allowed to stir under 1 atm of argon at 150°C for 24 h (the tube is connected to the Schlenk line which is filled with argon so that CO2 can be released to air).

References


PubMed Literature


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