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CAS RN: 2937-50-0 | Product Number: A1268

Allyl Chloroformate


Purity: >98.0%(T)
Synonyms:
  • Chloroformic Acid Allyl Ester
Documents:
25G
$37.00
≥20  ≥20 
500G
$268.00
2   4  

* Please contact our distributors or TCI to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.


Note:

This item is prohibited for air transportation.

Product Number A1268
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__4H__5ClO__2 = 120.53  
Physical State (20 deg.C) Liquid
Storage Temperature 0-10°C
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive,Heat Sensitive
CAS RN 2937-50-0
Reaxys Registry Number 773915
PubChem Substance ID 125308323
SDBS (AIST Spectral DB) 12076
MDL Number

MFCD00000648

Specifications
Appearance Colorless to Light yellow to Light orange clear liquid
Purity(GC) min. 95.0 %
Purity(Argentmetric Titration) min. 98.0 %
Properties (reference)
Boiling Point 110 °C
Flash point 31 °C
Specific Gravity (20/20) 1.14
Refractive Index 1.42
Solubility in water Soluble,Decomposes in contact with water
GHS
Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H330 : Fatal if inhaled.
H301 : Toxic if swallowed.
H314 : Causes severe skin burns and eye damage.
H226 : Flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 : Wear respiratory protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
Related Laws:
RTECS# LQ5775000
Transport Information:
UN Number UN1722
Class 6.1 / 3,8
H.S.code* 2915.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Protection of Alcohols
References

The allyloxycarbonyl group for alcohol protection: quantitative removal or transformation into allyl protecting group via π-allyl complexes of palladium

F. Guibe, Y. S. M'leux, Tetrahedron Lett. 1981, 22, 3591.


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