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CAS RN: 10465-81-3 | Product Number: A1051

1,1'-(Azodicarbonyl)dipiperidine


Purity: >98.0%(N)
Synonyms:
  • ADDP
Documents:
5G
£37.00
2   ≥40 
25G
£128.00
5   ≥40 

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*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).


Product Number A1051
Purity / Analysis Method >98.0%(N)
Molecular Formula / Molecular Weight C__1__2H__2__0N__4O__2 = 252.32  
Physical State (20 deg.C) Solid
CAS RN 10465-81-3
Reaxys Registry Number 261917
PubChem Substance ID 87562542
MDL Number

MFCD00010111

Specifications
Appearance Light yellow to Brown powder to crystal
Purity(with Total Nitrogen) min. 98.0 %
Melting point 134.0 to 137.0 °C
Properties (reference)
Melting Point 136 °C
Solubility (soluble in) Toluene
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P261 : Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
Related Laws:
Transport Information:
HS Number 2933399990
Application
Mitsunobu Reaction

References

N,N,N',N'-Tetramethylazodicarboxamide (TMAD), A New Versatile Reagent for Mitsunobu Reaction. Its Application to Synthesis of Secondary Amines

T. Tsunoda, J. Otsuka, Y. Yamamiya, S. Ito, Chem. Lett. 1994, 23, 539.

1,1'-(Azodicarbonyl)dipiperidine-tributylphosphine, a new reagent system for Mitsunobu Reaction

T. Tsunoda, Y. Yamamiya, S. Ito, Tetrahedron Lett. 1993, 34, 1639.


Application
Oxidation
References

Efficient Methods for Oxidation of Alcohols

K. Narasaka, A. Morikawa, K. Saigo, T. Mukaiyama, Bull. Chem. Soc. Jpn. 1977, 50, 2773.


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