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CAS RN: 578-66-5 | Product Number: A0419

8-Aminoquinoline


Purity: >98.0%(GC)(T)
Synonyms:
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Product Number A0419
Purity / Analysis Method >98.0%(GC)(T)
Molecular Formula / Molecular Weight C__9H__8N__2 = 144.18  
Physical State (20 deg.C) Solid
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive
CAS RN 578-66-5
Reaxys Registry Number 114474
PubChem Substance ID 87562053
SDBS (AIST Spectral DB) 3373
MDL Number

MFCD00006809

Specifications
Appearance White to Yellow to Green powder to crystal
Purity(GC) min. 98.0 %
Purity(Nonaqueous Titration) min. 98.0 %
Melting point 63.0 to 67.0 °C
Solubility in Methanol almost transparency
Properties (reference)
Melting Point 65 °C
Boiling Point 145 °C/2 mmHg
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
Related Laws:
EC Number 209-427-9
RTECS# VA9627000
Transport Information:
HS Number 2933499090
Application
A Directing Group Introducing Agent Useful for the C-H Activation at ortho-Position

References

1)Palladium-Catalyzed Direct ortho-Alkynylation of Aromatic Carboxylic Acid Derivatives

Y. Ano, M. Tobisu, N. Chatani, Org. Lett. 2012, 14, 354.

2)Nickel-Catalyzed Direct Alkylation of C–H Bonds in Benzamides and Acrylamides with Functionalized Alkyl Halides via Bidentate-Chelation Assistance

Y. Aihara, N. Chatani, J. Am. Chem. Soc. 2013, 135, 5308.

3)Ni(II)-Catalyzed Oxidative Coupling between C(sp2)–H in Benzamides and C(sp3)–H in Toluene Derivatives

Y. Aihara, M. Tobisu, Y. Fukumoto, N. Chatani, J. Am. Chem. Soc. 2014, 136, 15509.

4)Rhodium-Catalyzed Alkylation of C–H Bonds in Aromatic Amides with Styrenes via Bidentate–Chelation Assistance

K. Shibata, T. Yamaguchi, N. Chatani, Org. Lett. 2015, 17, 3584.


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