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CAS RN: 108-22-5 | Product Number: A0035

Isopropenyl Acetate


Purity: >98.0%(GC)
Synonyms:
  • Acetic Acid Isopropenyl Ester
Documents:
25ML
£12.00
3   39  
500ML
£24.00
1   ≥40 

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Product Number A0035
Purity / Analysis Method >98.0%(GC)
Molecular Formula / Molecular Weight C__5H__8O__2 = 100.12  
Physical State (20 deg.C) Liquid
CAS RN 108-22-5
Reaxys Registry Number 1280347
PubChem Substance ID 87561738
SDBS (AIST Spectral DB) 1423
Merck Index (14) 5203
MDL Number

MFCD00008709

Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 98.0 %
Properties (reference)
Melting Point -93 °C
Boiling Point 97 °C
Flash point 16 °C
Specific Gravity (20/20) 0.92
Refractive Index 1.40
Solubility (miscible with) Benzene,Ether
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H319 : Causes serious eye irritation.
H225 : Highly flammable liquid and vapour.
Precautionary Statements P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 : Keep container tightly closed.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
Related Laws:
EC Number 203-562-7
RTECS# UD4200000
Transport Information:
UN Number UN2403
Class 3
Packing Group II
HS Number 2915390090
Application
Acetylation of Alcohols via Transesterification using Acetylating Reagents

References

1)Acylation of Alcohols and Amines with Vinyl Acetates Catalyzed by Cp*2Sm(thf)2

Y. Ishii, M. Takeno, Y. Kawasaki, A. Muromachi, Y. Nishiyama, S. Sakaguchi, J. Org. Chem. 1996, 61, 3088.

2)Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols

P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


Application
Acetylation of Alcohols using Acetylating Reagents and Acid Catalysts

References

1)Total Synthesis of the Proposed Structure of Briarellin J

M. T. Crimmins, M. C. Mans, A. D. Rodríguez, Org. Lett. 2010, 12, 5028.

2)Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols

P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


PubMed Literature


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