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CAS RN: 14152-97-7 | Product Number: A5514

2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl Isothiocyanate [for HPLC Labeling]

Purity: >98.0%(HPLC)(N)
  • GITC
7   ≥20 
7   ≥20 

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Product Number A5514
Purity / Analysis Method >98.0%(HPLC)(N)
Molecular Formula / Molecular Weight C__1__5H__1__9NO__9S = 389.38  
Physical State (20 deg.C) Solid
Condition to Avoid Light Sensitive,Moisture Sensitive
CAS RN 14152-97-7
Reaxys Registry Number 56699
PubChem Substance ID 87563161
MDL Number


Appearance White to Almost white powder to crystal
Purity(HPLC) min. 98.0 area%
Purity(with Total Nitrogen) min. 98.0 %
Melting point 113.0 to 117.0 °C
Specific rotation [a]20/D -2.0 to -5.0 deg(C=1,methylene chloride)
Solubility in Dichloromethane almost transparency
Effect test of HPLC derivatization Effective as labeling agent for DL-Valine.
Properties (reference)
Melting Point 116 °C
Solubility (soluble in) dichloromethane
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Precautionary Statements P261 : Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 : Wear respiratory protection.
P342 + P311 : If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
Related Laws:
Transport Information:
HS Number 2940000080
HPLC Labeling Reagent for Amines

The compound 1 easily reacts with an amino group to form the corresponding 2,4-dinitrophenylamine derivative. The resultant derivative is stable and can reach the detector without any decomposition under reversed phase HPLC. An excellent chromatogram can be obtained by measuring at 254 nm, an absorption wavelength that is generally used for UV detection. Application examples:[Amines]A sample (free amine) 1 mg, chloroform 1 mL, and labeling regent 1 (1 eq. excess amount of the sample) are mixed, and incubated at 6 ºC for 1 h. After cooling to room temperature, use it as an HPLC sample. 1 is also used for derivatization of amino acids.1,2)[Others]Aminoglycosides3)TCI Products Pamphlet


1)T. Kinoshita, Y. Kasahara, N. Nimura, J. Chromatogr. 1981, 210, 77.

2)A. J. Sedman, J. Gal, J. Chromatogr. 1983, 278, 199.

3)H. Nishi, N. Fujimura, H. Yamaguchi, T. Fukuyama, J. Chromatogr. 1991, 539, 71.

PubMed Literature

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